1 ноември 2023
Yordanova I., Hristov S., Kolev H., Todorova S., Naydenov A..
(
Антон Найденов;
Илияна Христова;
Силвия Тодорова;
Станислав Христов;
Христо Колев;
)
Abstract
Series of mono- and bi-component cobalt and manganese supported on ion-exchanged clinoptilolite catalysts were prepared by impregnation method. They were characterized by X-ray diffraction (XRD), N2 adsorption-desorption, Fourier transform infrared spectroscopy (FTIR), temperature-programmed reduction (TPR), and X-ray photoelectron spectroscopy (XPS). The catalysts were tested in the reaction of complete oxidation of n-hexane. The highest catalytic activity was shown by the two-component catalyst containing 15 % of cobalt and 5 % of manganese oxides, which is due to the optimal ratio between the cation pairs Co2+/Co3+ and Mn3+/Mn4+ at Co/Mn = 1 on the surface calculated from XPS data and the presence of Co3O4.
Catalysis Today, 423, 1, ELSEVIER, 2023, DOI:10.1016/j.cattod.2023.114267, 114267. SJR (Scopus):1.05, JCR-IF (Web of Science):6.562 Q1, не оглавява ранглистата (Web of Science)
https://www.sciencedirect.com/science/article/pii/S0920586123002912
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